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A Si-Based Benzylic 1,4-Rearrangement/Cyclization Reaction
[Figure: see text] The trans-selective hydrosilylation of ynones (1) yields β-silylated enones (2) that undergo a benzylic 1,4-rearrangement/cyclization reaction in the presence of base, yielding 2,5-dihydro-1,2-oxasiloles (3).
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2009
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2640427/ https://ncbi.nlm.nih.gov/pubmed/19125665 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802289f |
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