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Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates

A simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite(®) resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones rema...

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Hlavní autoři: Basu, Basudeb, Mandal, Bablee, Das, Sajal, Das, Pralay, Nanda, Ashis K
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2008
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2633666/
https://ncbi.nlm.nih.gov/pubmed/19190744
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.4.53
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