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Interference in acetylene intersystem crossing acts as the molecular analog of Young's double-slit experiment

We report on an experimental approach that reveals crucial details of the composition of singlet-triplet mixed eigenstates in acetylene. Intersystem crossing in this prototypical polyatomic molecule embodies the mixing of the lowest excited singlet state (S(1)) with 3 triplet states (T(1), T(2), and...

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Detalhes bibliográficos
Main Authors: de Groot, Mattijs, Field, Robert W., Buma, Wybren J.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2632712/
https://ncbi.nlm.nih.gov/pubmed/19179288
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0809159106
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