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Enthalpy (ΔH) and Entropy (ΔS) for π-Stacking Interactions in near-Sandwich Configurations: The Relative Importance of Electrostatic, Dispersive, and Charge-Transfer Effects
Interactions between two aromatic rings with various substituents in a near-sandwich configuration have been quantitatively studied using the triptycene derived molecular models. This model system allows a stacking arrangement of two arenes to assume a near perfect face-to-face configuration in its...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2631381/ https://ncbi.nlm.nih.gov/pubmed/17338571 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo062526t |
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