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Identification of the Substrate Radical Intermediate Derived from Ethanolamine During Catalysis by Ethanolamine Ammonia-Lyase

Rapid-mix freeze-quench (RMFQ) methods and electron paramagnetic resonance (EPR) spectroscopy have been used to characterize the steady-state radical in the deamination of ethanolamine catalyzed by adenosylcobalamin (AdoCbl)-dependent ethanolamine ammonia-lyase (EAL). EPR spectra of the radical inte...

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Autores principales: Bender, Güneş, Poyner, Russell R., Reed, George H.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2631207/
https://ncbi.nlm.nih.gov/pubmed/18826329
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi801316v
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