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Direct Stereocontrolled Synthesis of 3-Amino-3-deoxy-β-Mannopyranosides: Importance of the Nitrogen Protecting Group on Stereoselectivity

The highly stereocontrolled synthesis of the 3-amino-3-deoxy-β-mannopyranosides is achieved by means of thioglycoside donors protected with a 4,6-O-benzylidene or alkylidene acetal and a benzylidene imine group. Among the various nitrogen protecting groups investigated only the Schiff’s base was fou...

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Detalhes bibliográficos
Main Authors: Crich, David, Xu, Huadong
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2621320/
https://ncbi.nlm.nih.gov/pubmed/17567072
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo070473p
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