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Structures and reaction pathways of the molybdenum centres of sulfite-oxidizing enzymes by pulsed EPR spectroscopy

SOEs (sulfite-oxidizing enzymes) are physiologically vital and occur in all forms of life. During the catalytic cycle, the five-co-ordinate square pyramidal oxo-molybdenum active site passes through the Mo(V) state, and intimate details of the structure can be obtained from variable frequency pulsed...

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Detalhes bibliográficos
Main Authors: Enemark, John H., Astashkin, Andrei V., Raitsimring, Arnold M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2613767/
https://ncbi.nlm.nih.gov/pubmed/19021510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1042/BST0361129
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