Φορτώνει......
Scope and Mechanism of Formal S(N)2′ Substitution Reactions of a Monomeric Imidozirconium Complex with Allylic Electrophiles
The zirconium imido complex Cp(2)(THF)Zr = NSi(t-Bu)Me(2) (1) reacts with allylic ethers, chlorides, and bromides to give exclusively the products of the S(N)2′ reaction; i.e., attack at the allylic position remote from the leaving group with migration of the double bond. The primary amine products...
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| Κύριοι συγγραφείς: | , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2008
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2593937/ https://ncbi.nlm.nih.gov/pubmed/18327942 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja7106096 |
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