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Revisiting the Hirao Cross-coupling: Improved Synthesis of Aryl and Heteroaryl Phosphonates

The palladium-catalyzed cross-coupling of dialkylphosphite with aromatic electrophiles (Hirao coupling) was re-investigated. Some limitations in terms of palladium loadings and substrate reactivity are alleviated with the use of Pd(OAc)(2) complexed to 1,1′-bis(diphenylphosphino)ferrocene (dppf) as...

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Bibliografski detalji
Glavni autori: Belabassi, Yamina, Alzghari, Saeed, Montchamp, Jean-Luc
Format: Artigo
Jezik:Inglês
Izdano: 2008
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2587344/
https://ncbi.nlm.nih.gov/pubmed/19156189
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2008.07.020
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