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Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle

[Figure: see text] The Resonance Raman spectra of the hydroperoxo complex of camphor-bound CYP101 have been obtained by cryoradiolytic reduction of the oxygenated ferrous form that had been rapidly frozen in water-glycerol frozen solution; EPR spectroscopy was employed to confirm the identity of the...

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Библиографические подробности
Главные авторы: Mak, Piotr J., Denisov, Ilia G., Victoria, Doreen, Makris, Thomas M., Deng, Tianjing, Sligar, Stephen G., Kincaid, James R.
Формат: Artigo
Язык:Inglês
Опубликовано: 2007
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC2574425/
https://ncbi.nlm.nih.gov/pubmed/17461587
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja071426h
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