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A porphyrin complex of Gold(I): (Phosphine)gold(I) azides as cation precursors
A silver- and Brönsted acid-free protocol for generating the (tricyclohexylphosphine)gold(I) cation from the corresponding azide complexes is disclosed. The gold(I) cations so liberated are trapped by complexation with octaethylporphyrin. The first structurally authenticated gold(I) porphyrin comple...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2567207/ https://ncbi.nlm.nih.gov/pubmed/18780788 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0806520105 |
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