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Photochemistry and electron-transfer mechanism of transition metal oxalato complexes excited in the charge transfer band

The photoredox reaction of trisoxalato cobaltate (III) has been studied by means of ultrafast extended x-ray absorption fine structure and optical transient spectroscopy after excitation in the charge-transfer band with 267-nm femtosecond pulses. The Co–O transient bond length changes and the optica...

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Detalhes bibliográficos
Main Authors: Chen, Jie, Zhang, Hua, Tomov, Ivan V., Ding, Xunliang, Rentzepis, Peter M.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2563110/
https://ncbi.nlm.nih.gov/pubmed/18832175
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0806990105
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