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Selective DNA Strand Scission with Binuclear Copper Complexes: Implications for an Active Cu(2)-O(2) Species
A homologous series of binuclear copper(II) complexes [Cu(II)(2)(Nn)(Y)(2)](2+) (1–3) (n = 3–5 and Y = (ClO(4))(−) or (NO(3))(−)) were studied to investigate the intermediate(s) responsible for selective DNA strand scission in the presence of MPA/O(2) (MPA = 3-mercaptopropanoic acid). While the N3 c...
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| Hlavní autoři: | , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2006
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2556057/ https://ncbi.nlm.nih.gov/pubmed/16719480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja061014t |
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