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Enantiomeric Free Radicals and Enzymatic Control of Stereochemistry in a Radical Mechanism: the Case of Lysine 2,3-aminomutases
The product of yjeK in Escherichia coli is a homolog of lysine 2,3-aminomutase (LAM) from Clostridium subterminale SB4, and both enzymes catalyze the isomerization of (S)- but not (R)-α-lysine by radical mechanisms. The turnover number for LAM from E. coli is 5.0 min(−1), 0.1% of the value for clost...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2553251/ https://ncbi.nlm.nih.gov/pubmed/17042480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi061328t |
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