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Rate Constants of Hydroperoxyl Radical Addition to Cyclic Nitrones: A DFT Study

Nitrones are potential synthetic antioxidants against the reduction of radical-mediated oxidative damage in cells, and as analytical reagent for the identification of HO(2)(•) and other such transient species. In this work, the PCM/B3LYP/6−31+G(d,p)//B3LYP/6−31G(d) and PCM/mPW1K/6−31+G(d,p) density...

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Detalhes bibliográficos
Main Authors: Villamena, Frederick A., Merle, John K., Hadad, Christopher M., Zweier*, Jay L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2544612/
https://ncbi.nlm.nih.gov/pubmed/17845014
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp073615s
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