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Decarboxylation of 2,2’-Bipyridinyl-4,4’-dicarboxylic acid diethyl ester during microwave synthesis of the corresponding trichelated ruthenium complex

Microwave reaction of RuCl(3) with 2,2’-bipyridinyl-4,4’-dicarboxylic acid diethyl ester (debpy) in ethylene glycol generated Ru(bpy)(3)(2+) instead of the expected Ru(debpy)(3)(2+). GCMS analysis of the head space revealed CO(2), and Ru(bpy)(3)(2+) was recovered from the filtrate. Further experimen...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Anderson, Thomas J., Scott, Jill R., Millett, Frank, Durham, Bill
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: 2006
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC2542503/
https://ncbi.nlm.nih.gov/pubmed/16676938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic060008v
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