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O(2) and N(2)O Activation by Binuclear, Trinuclear, and Tetranuclear Cu Clusters in Biology
Copper cluster sites in biology exhibit unique spectroscopic features reflecting exchange coupling between oxidized Cu’s and e(−) delocalization in mixed valent sites. These novel electronic structures play critical roles in O(2) binding and activation for electrophilic aromatic attack and H atom ab...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2532530/ https://ncbi.nlm.nih.gov/pubmed/17472331 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ar600060t |
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