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The Phenylpyruvate Tautomerase Activity of trans-3-Chloroacrylic Acid Dehalogenase: Evidence for an Enol Intermediate in the Dehalogenase Reaction?

The enzymatic conversion of cis- or trans-3-chloroacrylic acid to malonate semialdehyde is a key step in the bacterial degradation of the nematocide 1,3-dichloropropene. Two mechanisms have been proposed for the isomer-specific hydrolytic dehalogenases, cis- and trans-3-chloroacrylic acid dehalogena...

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Detalhes bibliográficos
Main Authors: Poelarends, Gerrit J., Johnson, William H., Serrano, Hector, Whitman, Christian P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2531067/
https://ncbi.nlm.nih.gov/pubmed/17661448
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi7007189
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