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Vibrational vs. translational energy in promoting a prototype metal–hydrocarbon insertion reaction
The reaction Y + CH(4) → HYCH(3) → YCH(2) + H(2) is initiated by C–H insertion involving a 20 ± 3 kcal/mol potential energy barrier. The reaction is studied in crossed molecular beams under two different conditions with nearly the same total energy. One experiment is carried out at a collision energ...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2529032/ https://ncbi.nlm.nih.gov/pubmed/18678904 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0801170105 |
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