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Palladium-Catalyzed Synthesis of Cyclopentane-Fused Benzocyclobutenes via Tandem Directed Carbopalladation/C–H Bond Functionalization

[Image: see text] A new Pd-catalyzed reaction for the stereoselective synthesis of cyclopentane-fused benzocyclobutenes is described. These transformations likely proceed via carbamate-directed carbopalladation followed by intramolecular C–H activation of an alkylpalladium intermediate. The mechanis...

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Detalhes bibliográficos
Main Authors: Bertrand, Myra Beaudoin, Wolfe, John P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2528069/
https://ncbi.nlm.nih.gov/pubmed/17616201
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071120f
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