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Vinyldiazolactone as a Vinylcarbene Precursor: Highly Selective C-H Insertion and Cyclopropanation Reactions

Vinylcarbenes are versatile synthetic intermediates, capable of asymmetric cyclopropanation and insertion into unactivated CH bonds. The vinyldiazolactone precursor to the metal vinylcarbene possesses superior stability in comparison to previously known vinyldiazoacetates and, for the first time, al...

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Detalhes bibliográficos
Main Authors: Bykowski, Darren, Wu, Kou-Hui, Doyle, Michael P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2526162/
https://ncbi.nlm.nih.gov/pubmed/17165748
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja066452e
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