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Two Novel 1,2,4,5-Tetrazines that Participate in Inverse Electron Demand Diels–Alder Reactions with an Unexpected Regioselectivity

Two new unsymmetrical 1,2,4,5-tetrazines, 3-methylsulfinyl-6-methylthio-1,2,4,5-tetrazine (4) and 3-(benzyloxycarbonyl)amino-6-methylsulfinyl-1,2,4,5-tetrazine (5), were prepared and scope of their participation in intermolecular inverse electron demand Diels–Alder reactions defined. As anticipated,...

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Detalhes bibliográficos
Main Authors: Hamasaki, Akiyuki, Ducray, Richard, Boger, Dale L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2525609/
https://ncbi.nlm.nih.gov/pubmed/16388634
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051832o
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