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Nitrosonium-Catalyzed Decomposition of S-Nitrosothiols in Solution: A Theoretical and Experimental Study
The decomposition of S-nitrosothiols (RSNO) in solution under oxidative conditions is significantly faster than can be accounted for by homolysis of the S-N bond. Here we propose a cationic chain mechanism in which nitrosylation of nitrosothiol produces a nitrosylated cation that, in turn, reacts wi...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2005
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2519156/ https://ncbi.nlm.nih.gov/pubmed/16076198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja050018f |
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