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Nitrosonium-Catalyzed Decomposition of S-Nitrosothiols in Solution: A Theoretical and Experimental Study

The decomposition of S-nitrosothiols (RSNO) in solution under oxidative conditions is significantly faster than can be accounted for by homolysis of the S-N bond. Here we propose a cationic chain mechanism in which nitrosylation of nitrosothiol produces a nitrosylated cation that, in turn, reacts wi...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Zhao, Yi-Lei, McCarren, Patrick R., Houk, K. N., Choi, Bo Yoon, Toone, Eric J.
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: 2005
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC2519156/
https://ncbi.nlm.nih.gov/pubmed/16076198
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja050018f
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