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Concerning the Selective Protection of (Z)-1,5-syn-Ene-diols and (E)-1,5-anti-Ene-diols as Allylic Triethylsilyl Ethers
[Image: see text] Treatment of unsaturated 1,5-diols 2 with TES-Cl (1.1 equiv), imidazole, and catalytic DMAP in 1 : 1 CH(2)Cl(2)-DMF at −78 °C effects selective silylation of the allylic alcohol with >95 : 5 chemoselectivity when the allylic and homoallylic alcohols are in similar steric environ...
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| Auteurs principaux: | , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2007
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2504016/ https://ncbi.nlm.nih.gov/pubmed/18027963 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol702588h |
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