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Synthesis of the Erythrina Alkaloid 3-Demethoxyerythratidinone. Novel Acid-induced Rearrangements of its Precursors

A new strategy for the synthesis of 3-demethoxyerythratidinone has been developed and is based on an extraordinarily facile intramolecular Diels-Alder reaction of a 2-imido substituted furan. During the course of the synthesis, several novel acid-induced rearrangement reactions were encountered.

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Detalhes bibliográficos
Main Authors: Wang, Qiu, Padwa, Albert
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2495026/
https://ncbi.nlm.nih.gov/pubmed/16468721
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0527330
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