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Synthesis of the Erythrina Alkaloid 3-Demethoxyerythratidinone. Novel Acid-induced Rearrangements of its Precursors
A new strategy for the synthesis of 3-demethoxyerythratidinone has been developed and is based on an extraordinarily facile intramolecular Diels-Alder reaction of a 2-imido substituted furan. During the course of the synthesis, several novel acid-induced rearrangement reactions were encountered.
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Main Authors: | , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2006
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2495026/ https://ncbi.nlm.nih.gov/pubmed/16468721 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0527330 |
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