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Valence isomerization of 2-phospha-4-silabicyclo[1.1.0]butane: a high-level ab initio study
The rearrangements for 2-phospha-4-silabicyclo[1.1.0]butane, analogous to the valence isomerization of the hydrocarbons bicyclobutane, 1,3-butadiene, and cyclobutene, were studied at the (U)QCISD(T)/6-311+G**//(U)QCISD/6-31G* level of theory. The monocyclic 1,2-dihydro-1,2-phosphasiletes are shown t...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Springer-Verlag
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2441497/ https://ncbi.nlm.nih.gov/pubmed/16642334 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00894-005-0041-7 |
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