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On the electronic nature of low-barrier hydrogen bonds in enzymatic reactions

The electronic nature of low-barrier hydrogen bonds (LBHBs) in enzymatic reactions is discussed based on combined low temperature neutron and x-ray diffraction experiments and on high level ab initio calculations by using the model substrate benzoylacetone. This molecule has a LBHB, as the intramole...

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Autors principals: Schiøtt, Birgit, Iversen, Bo Brummerstedt, Madsen, Georg Kent Hellerup, Larsen, Finn Krebs, Bruice, Thomas C.
Format: Artigo
Idioma:Inglês
Publicat: The National Academy of Sciences 1998
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC23598/
https://ncbi.nlm.nih.gov/pubmed/9788994
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