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A benzannulation strategy for the synthesis of phenols and heteroaromatic compounds based on the reaction of (trialkylsilyl)vinylketenes with lithium ynolates

(Trialkylsilyl)vinylketenes react with lithium ynolates to generate 3-(oxido)dienylketenes which undergo rapid 6π-electrocyclization. The ultimate products of this benzannulation are highly substituted resorcinol monosilyl ethers which are formed via a [1,3] carbon to oxygen silyl group shift. Furth...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Austin, Wesley F., Zhang, Yongjun, Danheiser, Rick L.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2008
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2350204/
https://ncbi.nlm.nih.gov/pubmed/19180173
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.10.113
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