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PEPTIDYL TRANSFERS IN GRAMICIDIN S BIOSYNTHESIS FROM ENZYME-BOUND THIOESTER INTERMEDIATES

The biosynthesis of the peptide antibiotic gramicidin S involves successive peptidyl transfer reactions between intermediates bound in thioester linkages to two active enzyme fractions, I and II. Fraction II activates and recemizes phenylalanine, and then initiates peptidyl transfer by catalyzing a...

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Autors principals: Gevers, Wieland, Kleinkauf, Horst, Lipmann, Fritz
Format: Artigo
Idioma:Inglês
Publicat: 1969
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC223469/
https://ncbi.nlm.nih.gov/pubmed/5260936
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