A carregar...

Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.

Na minha lista:
Detalhes bibliográficos
Main Authors: Allais, Florent, Boivin, Jean, Nguyen, Van Tai
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2213662/
https://ncbi.nlm.nih.gov/pubmed/18076755
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1860-5397-3-46
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!