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Substrate activation for O(2) reactions by oxidized metal centers in biology
The uncatalyzed reactions of O(2) (S = 1) with organic substrates (S = 0) are thermodynamically favorable but kinetically slow because they are spin-forbidden and the one-electron reduction potential of O(2) is unfavorable. In nature, many of these important O(2) reactions are catalyzed by metalloen...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2141783/ https://ncbi.nlm.nih.gov/pubmed/18003930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0704191104 |
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