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Inhibition of monoterpene cyclases by inert analogues of geranyl diphosphate and linalyl diphosphate
The tightly coupled nature of the reaction sequence catalyzed by monoterpene synthases has prevented direct observation of the topologically required isomerization step leading from geranyl diphosphate to the enzyme-bound, tertiary allylic intermediate linalyl diphosphate, which then cyclizes to the...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2140145/ https://ncbi.nlm.nih.gov/pubmed/17949678 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2007.09.008 |
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