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Efficient production of [n]rotaxanes by using template-directed clipping reactions

In this article, we report on the efficient synthesis of well defined, homogeneous [n]rotaxanes (n up to 11) by a template-directed thermodynamic clipping approach. By employing dynamic covalent chemistry in the form of reversible imine bond formation, [n]rotaxanes with dialkylammonium ion (–CH(2)NH...

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Detalles Bibliográficos
Main Authors: Wu, Jishan, Leung, Ken Cham-Fai, Stoddart, J. Fraser
Formato: Artigo
Idioma:Inglês
Publicado: National Academy of Sciences 2007
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2077244/
https://ncbi.nlm.nih.gov/pubmed/17947382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0705847104
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