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Effects of neighboring sulfides and pH on ester hydrolysis in thiol-acrylate photopolymers

Networks synthesized through thiol-acrylate photopolymerization or Michael-type addition step growth reactions contain esters with neighboring sulfide groups. Previous work has demonstrated that these esters are readily hydrolyzable at physiological pH. Here, the influence of the distance between th...

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Detalhes bibliográficos
Main Authors: Rydholm, Amber E., Anseth, Kristi S., Bowman, Christopher N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2041895/
https://ncbi.nlm.nih.gov/pubmed/17276150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.actbio.2006.12.001
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