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Homogenous Water Oxidation by a Di-μ-Oxo Dimanganese Complex in the Presence of Ce(4+)
O(2) evolution was observed upon mixing aqueous [(terpy)(H(2)O)Mn(O)(2)Mn(H(2)O)(terpy)](NO(3))(3) (1, terpy = 2,2′:6′,6″-terpyridine) with aqueous solutions of Ce(4+). However, when the solution of 1 was incubated at pH = 1 (by dissolving in dilute HNO(3)) before mixing with Ce(4+), very small amou...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2007
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1950133/ https://ncbi.nlm.nih.gov/pubmed/18542709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2007.02.020 |
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