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Tracking the excited-state time evolution of the visual pigment with multiconfigurational quantum chemistry

The primary event that initiates vision is the photoinduced isomerization of retinal in the visual pigment rhodopsin (Rh). Here, we use a scaled quantum mechanics/molecular mechanics potential that reproduces the isomerization path determined with multiconfigurational perturbation theory to follow t...

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Main Authors: Frutos, Luis Manuel, Andruniów, Tadeusz, Santoro, Fabrizio, Ferré, Nicolas, Olivucci, Massimo
Formato: Artigo
Idioma:Inglês
Publicado: National Academy of Sciences 2007
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC1876521/
https://ncbi.nlm.nih.gov/pubmed/17470789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0701732104
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