Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes

Protonation of the ortho-metalated ruthenium complexes RuH(H(2))(X)(P(i)Pr(3))(2) [X = 2-phenylpyridine (ph-py) (1), benzoquinoline (bq) (2)] and RuH(CO)(ph-py)(P(i)Pr(3))(2) (3) with [H(OEt(2))(2)](+)[BAr′(4)](−) (BAr′(4) = [(3,5-(CF(3))(2)C(6)H(3))(4)B]) under H(2) atmosphere yields the correspond...

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Autors principals: Toner, Andrew, Matthes, Jochen, Gründemann, Stephan, Limbach, Hans-Heinrich, Chaudret, Bruno, Clot, Eric, Sabo-Etienne, Sylviane
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2007
Matèries:
Coordination Chemistry of Saturated Molecules Special Feature
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC1855409/
https://ncbi.nlm.nih.gov/pubmed/17360384
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0608979104
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