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Theoretical study of the rhenium–alkane interaction in transition metal–alkane σ-complexes
Metal–alkane binding energies have been calculated for [CpRe(CO)(2)](alkane) and [(CO)(2)M(C(5)H(4))C [Image: see text] C(C(5)H(4))M(CO)(2)](alkane), where M = Re or Mn. Calculated binding energies were found to increase with the number of metal–alkane interaction sites. In all cases examined, the m...
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| Main Authors: | , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
National Academy of Sciences
2007
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1855367/ https://ncbi.nlm.nih.gov/pubmed/17442751 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0610295104 |
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