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The mechanism for proton-coupled electron transfer from tyrosine in a model complex and comparisons with Y(Z) oxidation in photosystem II.
In the water-oxidizing reactions of photosystem II (PSII), a tyrosine residue plays a key part as an intermediate electron-transfer reactant between the primary donor chlorophylls (the pigment P(680)) and the water-oxidizing Mn cluster. The tyrosine is deprotonated upon oxidation, and the coupling b...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2002
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1693043/ https://ncbi.nlm.nih.gov/pubmed/12437887 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2002.1142 |
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