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Toward elimination of discrepancies between theory and experiment: The rate constant of the atmospheric conversion of SO(3) to H(2)SO(4)

The hydration rate constant of sulfur trioxide to sulfuric acid is shown to depend sensitively on water vapor pressure. In the 1:1 SO(3)-H(2)O complex, the rate is predicted to be slower by about 25 orders of magnitude compared with laboratory results [Lovejoy, E. R., Hanson, D. R. & Huey, L. G....

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Autores principales: Loerting, Thomas, Liedl, Klaus R.
Formato: Artigo
Lenguaje:Inglês
Publicado: The National Academy of Sciences 2000
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC16788/
https://ncbi.nlm.nih.gov/pubmed/10922048
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