Resolving intermediates in biological proton-coupled electron transfer: A tyrosyl radical prior to proton movement
The coupling of proton chemistry with redox reactions is important in many enzymes and is central to energy transduction in biology. However, the mechanistic details are poorly understood. Here, we have studied tyrosine oxidation, a reaction in which the removal of one electron from the amino acid i...
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| Publié dans: | Proc Natl Acad Sci U S A |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
2003
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC166381/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/12855767/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.1530926100 |
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