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Resolving intermediates in biological proton-coupled electron transfer: A tyrosyl radical prior to proton movement

The coupling of proton chemistry with redox reactions is important in many enzymes and is central to energy transduction in biology. However, the mechanistic details are poorly understood. Here, we have studied tyrosine oxidation, a reaction in which the removal of one electron from the amino acid i...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Faller, Peter, Goussias, Charilaos, Rutherford, A. William, Un, Sun
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: National Academy of Sciences 2003
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC166381/
https://ncbi.nlm.nih.gov/pubmed/12855767
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1530926100
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