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Quantum catalysis in B(12)-dependent methylmalonyl-CoA mutase: experimental and computational insights
B(12)-dependent methylmalonyl-CoA mutase catalyses the interchange of a hydrogen atom and the carbonyl-CoA group on adjacent carbons of methylmalonyl-CoA to give the rearranged product, succinyl-CoA. The first step in this reaction involves the transient generation of cofactor radicals by homolytic...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
The Royal Society
2006
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1647305/ https://ncbi.nlm.nih.gov/pubmed/16873121 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1866 |
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