Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents

The concept of initiators for continuous activator regeneration (ICAR) in atom transfer radical polymerization (ATRP) is introduced, whereby a constant source of organic free radicals works to regenerate the Cu(I) activator, which is otherwise consumed in termination reactions when used at very low...

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Autori principali: Matyjaszewski, Krzysztof, Jakubowski, Wojciech, Min, Ke, Tang, Wei, Huang, Jinyu, Braunecker, Wade A., Tsarevsky, Nicolay V.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2006
Soggetti:
Polymerization Special Feature
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC1622823/
https://ncbi.nlm.nih.gov/pubmed/17032773
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0602675103
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