The decomposition of peroxynitrite to nitroxyl anion (NO(−)) and singlet oxygen in aqueous solution

The mechanism of decomposition of peroxynitrite (OONO(−)) in aqueous sodium phosphate buffer solution at neutral pH was investigated. The OONO(−) was synthesized by directly reacting nitric oxide with superoxide anion at pH 13. The hypothesis was explored that OONO(−), after protonation at pH 7.0 to...

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Veröffentlicht in:	Proc Natl Acad Sci U S A
Hauptverfasser:	Khan, Ahsan Ullah, Kovacic, Dianne, Kolbanovskiy, Alexander, Desai, Mehul, Frenkel, Krystyna, Geacintov, Nicholas E.
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	National Academy of Sciences 2000
Schlagworte:	Physical Sciences
Online-Zugang:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC16178/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/10716721/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.050587297
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