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The peptide-catalyzed stereospecific synthesis of tetroses: A possible model for prebiotic molecular evolution

Using a water-based prebiotic model of sugar synthesis involving glycolaldehyde self-condensation, we demonstrate that homochiral l-dipeptide catalysts lead to the stereospecific syntheses of tetroses. The asymmetric effect is largest for erythrose, which may reach a d-enantiomeric excess of >80%...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Weber, Arthur L., Pizzarello, Sandra
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: National Academy of Sciences 2006
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC1568914/
https://ncbi.nlm.nih.gov/pubmed/16905650
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0602320103
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