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Amplification of enantiomeric concentrations under credible prebiotic conditions

Solutions with as little as 1% enantiomeric excess (ee) of d- or l-phenylalanine are amplified to 90% ee (a 95/5 ratio) by two successive evaporations to precipitate the racemate. Such a process on the prebiotic earth could lead to a mechanism by which meteoritic chiral α-alkyl amino acids could for...

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Detalhes bibliográficos
Main Authors: Breslow, Ronald, Levine, Mindy S.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1559738/
https://ncbi.nlm.nih.gov/pubmed/16938839
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0605863103
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