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Rearrangements and Stereomutations of Metallacycles Derived from Allenes and Imidozirconium Complexes
The mechanisms of the rearrangements and stereoinversion of azametallacyclobutenes generated via [2+2] cycloaddition of allenes and imidozirconium complexes have been studied. Metallacycles derived from allenes bearing β-hydrogen atoms racemize at room temperature by reversible β-hydride elimination...
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| Главные авторы: | , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2005
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1444910/ https://ncbi.nlm.nih.gov/pubmed/15701010 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja045607k |
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