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Self-fulfilling cavitands: Packing alkyl chains into small spaces

The present research was undertaken to determine the conformations of alkyl groups that are forced into small spaces. Unbranched alkyl groups assume fully extended conformations in the free space of solutions, because any bends in the structure create steric clashes between hydrogens along the chain...

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Detalhes bibliográficos
Main Authors: Purse, Byron W., Rebek, Julius
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1413836/
https://ncbi.nlm.nih.gov/pubmed/16477037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0511149103
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