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Self-fulfilling cavitands: Packing alkyl chains into small spaces

The present research was undertaken to determine the conformations of alkyl groups that are forced into small spaces. Unbranched alkyl groups assume fully extended conformations in the free space of solutions, because any bends in the structure create steric clashes between hydrogens along the chain...

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Autori principali: Purse, Byron W., Rebek, Julius
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2006
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC1413836/
https://ncbi.nlm.nih.gov/pubmed/16477037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0511149103
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