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A novel reduction of diketones with i-RMgBr catalyzed by Cp(2)TiCl(2) and deoxygenation of sulfoxides by Cp(2)TiCl(2)/Al system
α-diketones and β-diketones react with Grignard reagents in the presence of a catalytic amount of Cp(2)TiCl(2) to yield α-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp(2)TiCl(2)/Al system. The possible mechanisms are also discussed.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Zhejiang University Press
2004
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1388720/ https://ncbi.nlm.nih.gov/pubmed/15362186 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1631/jzus.2004.1175 |
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