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Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes
Electron-deficient imines are shown to insert into the zirconium-carbon bond of azazirconacyclobutenes to generate new six-membered ring metallacycles. On heating, these expanded zirconacycles undergo a retro-[4 + 2] cycloaddition to generate α,β-unsaturated imines in excellent yields and novel, ful...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1383655/ https://ncbi.nlm.nih.gov/pubmed/16508694 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0497994 |
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